Mechanisms of elimination and substitution reactions. Spontaneous solvolysis reactions via carbanion and carbocation intermediates
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چکیده
منابع مشابه
The Kinetics and Mechanisms of Substitution Reactions of Trans-[Co(en)2CNCl]+ in Binary Mixed Solvent
The kinetics and mechanisms of the substitution reactions of trans-[Co(en)2CNCl]+ with unidentate anions, , CN¯, I¯, , Br¯ and SCN¯ in 60% v/v DMF-H2O binary solvent at 40.0±0.2 °C were studied spectrophotometrically. An Id mechanism was assigned for the replacement of chlorine by , CN¯ and I¯, an Ia one for...
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متن کاملthe kinetics and mechanisms of substitution reactions of trans-[co(en)2cncl]+ in binary mixed solvent
the kinetics and mechanisms of the substitution reactions of trans-[co(en)2cncl]+ with unidentate anions, , cn¯, i¯, , br¯ and scn¯ in 60% v/v dmf-h2o binary solvent at 40.0±0.2 °c were studied spectrophotometrically. an id mechanism was assigned for the replacement of chlorine by , cn¯ and i¯, an ia one for the entry of and scn¯, and a d mechanism for br¯ entry. comparing the interchange ra...
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ژورنال
عنوان ژورنال: Journal of Physical Organic Chemistry
سال: 1999
ISSN: 0894-3230,1099-1395
DOI: 10.1002/(sici)1099-1395(199902)12:2<116::aid-poc102>3.0.co;2-8